Perikon diode
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At Fig. 11 we have the Perikon Detector developed by G. W. Pickard. This detector consists of two crystals--copper pyrites (Cu Fe S2) and zincite (zinc oxide ZnO), held in firm contact against each other in the manner shown. The copper pyrite crystal is mounted in a cup mounted on a spring-actuated rod provided with a suitable knob, by which it can be swung in any direction. Zincite crystals are mounted in a large cup containing several pockets, the mounting of both of the minerals being effected with a low fusing solder, Wood's metal or Hugonium alloy. The action of the Perikon detector is supposed to be based on the rectifying principle previously described; that is, it will pass current in one direction but not in the other, and thus the incoming radio frequency oscillating (alternating) currents in the aerial are rectified and caused to give a sound in the high resistance 'phones connected to the detector. This detector is invariably used with a battery of about two cells and the potential applied regulated by a potentiometer. When using a battery the polarity of the current must be such that the positive wire is connected to the copper pyrite crystal. - The Electrical Experimenter, January, 1917

